The French giants hold a 3-1 lead heading into Tuesday's (15.04.25) quarter-final second leg and the coach insists that his team won't be afraid of the Villa Park cauldron as they bid to seal a place in the last four.
Enrique said: "For us, it is always a pleasure to play and compete in a stadium like this, with so much history.
"We love playing football. Our teams and supporters are accustomed to this. It is going to be a big match, there is certainly no problem with the atmosphere. It is a motivation, more than anything."
PSG are in a strong position in the tie but Enrique stressed that they still have a long way to go before they can start planning for the semi-final.
The Spanish manager said: "The tie isn’t over, it is still open. It is going to be difficult. We are prepared to suffer if necessary to get our aim and win this match.
"At the end of the match there will be only one team in the semi-final and the other team is out. That is the beauty of the competition.
"Aston Villa are down at the moment but the tie remains very open and both teams know. There is no over-confidence in our side, we have got motivation to overcome the problems Aston Villa can set us and reach our aim of winning the match.
"When people talk about favourites before the match... the road of the Champions League is full of favourites who have been knocked out. We knew we were better and deserved to win in the first leg, but there is a second story. Who is going to win tomorrow?
"We have the advantage, but we don’t speculate about certainties. If Aston Villa are better than us they can overcome us, so we need to show we deserve to be in the semi-final."